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欧盟POPS禁用物质清单 欧盟POPS检测指令 (EU)2019/1021 欧盟POPS检测实验室 持久性有机污染物POPs测试机构 POPs测试项目 持久性有机污染物检测项目 欧盟SCCP测试实验室 欧盟HBCDD测试实验室
POPs是英文Persistent Organic Pollutants的缩写,中文名称为“持久性有机污染物”,它是一类具有长期残留性、生物累积性、半挥发性和高毒性,并通过各种环境介质(大气、水、生物等)能够长距离迁移对人类健康和环境具有严重危害的天然的或人工合成的有机污染物。
为履行公约中的承诺,欧盟颁布了POPs管控法规(EC)No 850/2004,并于2019年发布新版管控法规(EU) 2019/1021。该法规管控了一系列持久性有机污染物,其中附件I所管控的物质无论是单独存在,还是以混合物形式存在,抑或是存在于物品中,均是禁止制造、投放市场和使用的,除非符合豁免条款。
1.四溴二苯醚
2.五溴二苯醚
3.六溴二苯醚
4.七溴二苯醚
5.十溴二苯醚
6.全氟辛烷磺酸及其衍生物(PFOS)
7.DDT2,2-双(4-氯苯基)-1,1,1-三氯乙烷
8.氯丹
9.六氯环己烷,包括林丹
10.狄氏剂
11.异狄氏剂
12.七氯
13.硫丹
14.六氯苯
15.十氯酮
16.艾氏剂
17.五氯苯
18.多氯联苯(PCB)
19.灭蚁灵
20.毒杀芬
21.六溴联苯
22.六溴环十二烷
23.六氯丁二烯
24.五氯苯酚及其盐类和酯类
25.多氯化萘
26.短链氯化石蜡
27.全氟辛酸(PFOA)及其盐和相关化合物
(i)全氟辛酸,包括其支链同分异构体;
(ii)全氟辛酸的盐类;
(iii)全氟辛酸相关化合物是指任何可以分解产生PFOA的物质,包括任何碳链结构含有支链或直链的全氟庚烷基且具有(C7F15)C作为结构要素之一的物质(包括盐类和聚合物)。
下列物质不属于全氟辛酸相关化合物:
(i)C8F17-X, X = F, Cl, Br;
(ii)具有CF3[CF2]n-R’结构的全氟聚合物,这里的R’可以是任何官能团, n> 16;
(iii)含8个及8个以上碳原子的全氟羧酸(包括它们的盐类、酯类、卤化物和酸酐);
(iv)含9个及9个以上碳原子个数的全氟烷基磺酸和全氟膦酸(包括它们的盐类、酯类、卤化物和酸酐);
(v)本附件中所列的全氟辛烷磺酸及其衍生物。
28.三氯杀螨醇
Part A
Substances listed in the Convention and in the Protocol as well as substances listed only in the Convention
Substance | CAS No | EC No | Specific exemption on intermediate use or other specification | ||||||||||||||||||||||||||||||||||||
Tetrabromodiphenyl ether C12H6Br4O |
40088-47-9 and others | 254-787-2 and others |
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Pentabromodiphenyl ether C12H5Br5O |
32534-81-9 and others | 251-084-2 and others |
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Hexabromodiphenyl ether C12H4Br6O |
36483-60-0 and others | 253-058-6 and others |
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Heptabromodiphenyl ether C12H3Br7O |
68928-80-3 and others | 273-031-2 and others |
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Bis(pentabromophenyl) ether (decabromodiphenyl ether; decaBDE) | 1163-19-5 | 214-604-9 |
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Perfluorooctane sulfonic acid and its derivatives (PFOS) C8F17SO2X (X = OH, Metal salt (O-M+), halide, amide, and other derivatives including polymers) |
1763-23-1 2795-39-3 29457-72-5 29081-56-9 70225-14-8 56773-42-3 251099-16-8 4151-50-2 31506-32-8 1691-99-2 24448-09-7 307-35-7 and others |
217-179-8 220-527-1 249-644-6 249-415-0 274-460-8 260-375-3 223-980-3 250-665-8 216-887-4 246-262-1 206-200-6 and others |
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DDT (1,1,1-trichloro-2,2-bis(4-chlorophenyl)ethane) | 50-29-3 | 200-024-3 | — | ||||||||||||||||||||||||||||||||||||
Chlordane | 57-74-9 | 200-349-0 | — | ||||||||||||||||||||||||||||||||||||
Hexachlorocyclohexanes, including lindane | 58-89-9 | 200-401-2 | — | ||||||||||||||||||||||||||||||||||||
319-84-6 | 206-270-8 | ||||||||||||||||||||||||||||||||||||||
319-85-7 | 206-271-3 | ||||||||||||||||||||||||||||||||||||||
608-73-1 | 210-168-9 | ||||||||||||||||||||||||||||||||||||||
Dieldrin | 60-57-1 | 200-484-5 | — | ||||||||||||||||||||||||||||||||||||
Endrin | 72-20-8 | 200-775-7 | — | ||||||||||||||||||||||||||||||||||||
Heptachlor | 76-44-8 | 200-962-3 | — | ||||||||||||||||||||||||||||||||||||
Endosulfan |
115-29-7 959-98-8 33213-65-9 |
204-079-4 |
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Hexachlorobenzene | 118-74-1 | 204-273-9 | — | ||||||||||||||||||||||||||||||||||||
Chlordecone | 143-50-0 | 205-601-3 | — | ||||||||||||||||||||||||||||||||||||
Aldrin | 309-00-2 | 206-215-8 | — | ||||||||||||||||||||||||||||||||||||
Pentachlorobenzene | 608-93-5 | 210-172-0 | — | ||||||||||||||||||||||||||||||||||||
Polychlorinated Biphenyls (PCB) | 1336-36-3 and others | 215-648-1 and others |
Without prejudice to Directive 96/59/EC, articles already in use at the time of the entry into force of this Regulation are allowed to be used. Member States shall identify and remove from use equipment (e.g. transformers, capacitors or other receptacles containing liquid stocks) containing more than 0,005 % PCBs and volumes greater than 0,05 dm3, as soon as possible but no later than 31 December 2025. |
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Mirex | 2385-85-5 | 219-196-6 | — | ||||||||||||||||||||||||||||||||||||
Toxaphene | 8001-35-2 | 232-283-3 | — | ||||||||||||||||||||||||||||||||||||
Hexabromobiphenyl | 36355-01-8 | 252-994-2 | — | ||||||||||||||||||||||||||||||||||||
1 Hexabromocyclododecane ‘Hexabromocyclododecane’ means: hexabromocyclododecane, 1,2,5,6,9,10-hexabromocyclododecane and its main diastereoisomers: alpha-hexabromocyclododecane; beta-hexabromocyclododecane; and gamma-hexabromocyclododecane |
25637-99-4, 3194-55-6, 134237-50-6, 134237-51-7, 134237-52-8 |
247-148-4, 221-695-9 |
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Hexachlorobutadiene | 87-68-3 | 201-765-5 |
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Pentachlorophenol and its salts and esters | 87-86-5 and others | 201-778-6 and others | |||||||||||||||||||||||||||||||||||||
Polychlorinated naphthalenes (7) | 70776-03-3 and others | 274-864-4 and others |
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Alkanes C10-C13, chloro (short-chain chlorinated paraffins) (SCCPs) | 85535-84-8 and others | 287-476-5 |
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